一.四硫富瓦烯ttf羧酸衍生物的合成与性质分析;二.手性席夫碱双核锰配合物的合成与晶体结构-1. synthesis and property analysis of ttf carboxylic acid derivatives of tetrathiafulvalene; ii. synthesis and crystal structure of chiral schiff base binuclear manganese comp.docxVIP

目录摘要.................................................IAbstract................................................II目录...............................................III5立题思想.............................................18实验部分.................................................19一、主要仪器与试剂......................................19二、化合物的合成........................................201合成路线.............................................202化合物的合成与表征...................................21三、晶体结构测定........................................23结果与讨论.................................................241合成.................................................242目标产物的表征.......................................272．1红外光谱鉴定.......................................272．2元素分析...........................................272．3核磁共振...........................................272．4质谱...............................................282．5晶体结构...........................................293化合物的性质.........................................373．1紫外可见光谱.......................................373．2电化学研究.........................................38参考文献....................................................40第二部分手性席夫碱双核锰配合物的合成和晶体结构........46前言......................................................46实验部分....................................................48一、主要仪器及试剂......................................48二、化合物的合成........................................481合成路线.............................................482化合物合成与表征.....................................48三、晶体结构的测定......................................49结果与讨论.................................................501化合物的结构鉴定.....................................501．1红外光谱鉴定.......................................501．2晶体结构...........................................502化合物的性质.........................................60参考文献....................................................61附录：................................................63致谢..................................................64第一部分四硫富瓦烯(TTF)羧酸衍生物的合成与性质研究前言一般认为有机