a transient model for fuel cell cathode-water propagation behavior inside a cathode after a step potential瞬态模型对燃料电池cathode-water传播行为在一个阴极后一步的潜力.pdfVIP
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a transient model for fuel cell cathode-water propagation behavior inside a cathode after a step potential瞬态模型对燃料电池cathode-water传播行为在一个阴极后一步的潜力
Energies 2010, 3, 920-939; doi:10.3390/en3050920
OPEN ACCESS
energies
ISSN 1996-1073
/journal/energies
Article
A Transient Model for Fuel Cell Cathode-Water Propagation
Behavior inside a Cathode after a Step Potential
Der-Sheng Chan 1,* and Kan-Lin Hsueh 2
1 Department of Chemical and Materials Engineering, Lee-Ming Institute of Technology, Taishan,
Taipei, Taiwan
2 Department of Energy and Resources, National United University, Maioli, Taiwan ;
E-Mail: KanLinhsueh@ (K.H.)
* Author to whom correspondence should be addressed; E-Mail: dschan@;
Tel.: +886-2Ext. 2352; Fax: +886-2
Received: 9 March 2010; in revised form: 21 April 2010 / Accepted: 26 April 2010 /
Published: 30 April 2010
Abstract: Most of the voltage losses of proton exchange membrane fuel cells (PEMFC) are
due to the sluggish kinetics of oxygen reduction on the cathode and the low oxygen
diffusion rate inside the flooded cathode. To simulate the transient flooding in the cathode
of a PEMFC, a transient model was developed. This model includes the material
conservation of oxygen, vapor, water inside the gas diffusion layer (GDL) and
micro-porous layer (MPL), and the electrode kinetics in the cathode catalyst layer (CL).
The variation of hydrophobicity of each layer generated a wicking effect that moves water
from one layer to the other. Since the GDL, MPL, and CL are made of composite materials
with different hydrophilic and
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