有机化学的研究进展_黄培强.pdf

有机化学的研究进展 黄培强 1 唐功利 2 赵刚 2 岳建民 3 吴金波 2 田伟生2 1 2 3 ( 厦门大学化学学院； 中国科学院上海有机化学研究所； 中国科学院上海药物研究所) Advance in Organic Chemistry 1 2 2 3 Huang Peiqiang , Tang Gongli , Zhao Gang , Yue Jianmin , 2 2 Wu Jinbo , Tian Weisheng 1 2 ( Xiamen University, Shang Institute of Organic Chemistry, CAS, 3 Shanghai Institute of Metria Medica) In 2008 ，the organic chemistry in China have made great progress. This annual report presented some main research achievements related to organic reaction, organic synthetic chemistry, natural product chemistry, elemental organic chemistry and bio-synthetic chemistry which made by chemists in China mainland. The annual collected 19 metallic or organic molecular catalytic reactions which have been reported in international journals such as JACS, Angew. Chem., and so on. The metallic catalytic reaction mainly involved the palladium catalytic reaction including allylic amination, allylic substitution, arolyation of aniline, allene addition as well as domino reaction or multi-components reaction. Organic molecular catalytic reactions related to proline derivatives catalytic reactions. 29 new natural products included Pzewalskin B, Chlorahololides A and B, Machilaminosides A and B, Pre-schisanartanin, Paxdaphnines A and B, Daphlongeranines A and B, Macropodumines D and E, E-alstoscholarine, Walsuronoids A an