AuCu2O Schottky contact heterostructures with enhanced photocatalytic activity in dye decomposition and photoelectrochemical water splitting under visible light irradiation.pdfVIP
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AuCu2O Schottky contact heterostructures with enhanced photocatalytic activity in dye decomposition and photoelectrochemical water splitting under visible light irradiation.pdf
Journal of Alloys and Compounds 684 (2016) 445e452
Contents lists available at ScienceDirect
Journal of Alloys and Compounds
journal homepage: /locate/jalcom
Au/Cu2O Schottky contact heterostructures with enhanced photocatalytic activity in dye decomposition and photoelectrochemical water splitting under visible light irradiation
Weiwei Zhang a, Baoshun Wang b, Chenchun Hao a, Yujie Liang a, Honglong Shi a, Ling Ao a, Wenzhong Wang a, *
a School of Science, Minzu University of China, Beijing 10081, PR China b College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875, PR China
article info
Article history: Received 3 January 2016 Received in revised form 8 May 2016 Accepted 18 May 2016 Available online 19 May 2016
Keywords: Cuprous oxide Schottky contact Visible light Dye decomposition Water-splitting
abstract
In this work noble metal Au nanoparticles have been successfully deposited on the surface of Cu2O microcubes to construct close Au/Cu2O Schottky contact heterostructures, in which both an inner electronic ?eld from Au to Cu2O and a Schottky barrier are established at the interface of Au and Cu2O due to the Schottky junction. Bene?ting from this unique structure with synergistic effect of inner electronic ?eld and Schokkty barrier, the as-fabricated Au/Cu2O Schottky contact heterostructures exhibit enhanced photocatalytic activity to pure Cu2O microcubes in dye decomposition and water splitting under visible light illumination. The photodegradation rate of the as-constructed Au/Cu2O Schottky contact heterostructures for methyl orange (MO) is 1.2 times higher than that of pure Cu2O microcubes under visible light irradiation for 90 min. The photocurrent density of the as-prepared Au/Cu2O heterostructures
electrode reaches up to 30 mA cmà2, which is 3 times higher than that (10 mA cmà2) of pure Cu2O
microcube electrode at 1.23 V vs RHE. The enhanced photocatalytic activity of the as-constructed Au/ Cu2O Schottky contact heterostructures i
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