甲烷部分氧化lsf中空纤维膜反应器性能分析-performance analysis of lsf hollow fiber membrane reactor for methane partial oxidation.docxVIP
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甲烷部分氧化lsf中空纤维膜反应器性能分析-performance analysis of lsf hollow fiber membrane reactor for methane partial oxidation
山东理工大学硕士学位论文Abstractthe reactor packed with Ni-based catalyst respectively and the oxygen permeability of LSF hollow fiber membrane was studied. The inlet and outlet gas content was measured by gas chromatography. The results of POM reactionrevealed that the CH4 conversion, the selectivities of CO and H2 at 900℃ couldreach 99.9%, 50.0% and 59.3%, respectively. The H2/CO ratio in the product was close to 2. Oxygen permeabilit y of LSF hollow fiber membrane during the POM reaction could reach 9.6 mL·cm-2·min-1 and excellent chemical stability were observed in the stability test for 100h.Key words: mixed conductor; perovskite structure; hollow fiber membrane; oxygen permeation; syngas目 录摘 要 ............................................................................................................... IAbstract ..........................................................................................................II目录 .............................................................................................................. IV引言 ................................................................................................................ 1第一章 文献 综述 ............................................................................................ 21.1 混合 导体透 氧膜 ................................................................................ 21.1.1 透氧膜 的分 类 ......................................................................... 21.1.2 钙钛矿 陶瓷 透氧 膜的透 氧机 理 ................................................ 41.1.3 钙钛矿 型氧 离子/电子混 合导 体陶 瓷 材料的 制备方 法 .............. 71.1.4 钙钛矿 陶瓷 透氧 膜的制 备 ....................................................... 81.2 陶瓷 膜反应 器中 甲烷催 化部 分氧 化反应 ............................................ 81.2.1 陶瓷膜 反应 器的 种类及 应用 .................................................... 91.2.2 甲烷催 化部 分氧 化制合 成气 的机理 ....................................... 101.2.3 甲烷催 化反 应催 化剂的 选择 与制备 ....................................... 121.3 研究 路线与 内容 .....................
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