配位化学8.ppt

Heteroleptic Bis(phthalocyaninato) Rare Earth Complexes [MIII(Pc){Pc(?-OC5H11)4}] (M = Y, Sm-Lu) J. Jiang* et al., Chem. Commun., 2003, 1194. J. Jiang* et al., Helv. Chim. Acta., 2004, 87, 2581. J. Jiang* et al., Vibrational Spectroscopy., 2004,34, 283. M(Pc)(Pc*) (M = Sm…Lu, Y) The first molecular structure of chiral bis(phthalocyaninato) rare earth molecules Towards chiral sandwiches J. Jiang* et al., Chem. Commun., 2003, 1194. Chirality induced by adjusting the number and position of substituents The first molecular structure of chiral bis(phthalocyaninato) rare earth molecules EuIII(Pc){Pc(?-OC5H11)4} Chirality induced by adjusting the number and position of substituents Heteroleptic Tris(phthalocyaninato) Rare Earth Complexes (Pc)M(Pc)M[Pc(?-OC5H11)4] Pseudo-double-decker Structure of Phthalocyaninato Lead Complexes J. Jiang* et al., Inorg. Chem. 2004, 43, 7539. Tetrasubstituted Phthalocyaninato Lead Complexes Pb[Pc(?-OR)4] Pseudo-double-decker supramolecular structure in crystal of {Pb[Pc(?-OR)4]}2 J. Jiang* et al., Inorg. Chem. 2004, 43, 7539. Pseudo-double-decker supramolecular structure in crystal of Pb[Pc(?-OC5H11)4] in side view J. Jiang* et al., J. Phys. Chem. A, 2005, 109, 6363. Structures and Properties of Pb[Pc(?-OC5H11)4] : The Substitutional Effect Study Based on DFT Calculations Homoleptic “Pinwheel-Like” Rare Earth Double-Decker Complexes M[Pc(?-OC5H11)4 ]2 major isomer with C4h symmetry minor isomer with D4 symmetry J. Jiang* et al., Chem. Eur. J., 2005, 11, 7351. Molecular structure of “Pinwheel-Like” M[Pc(?-OC5H11)4 ]2 Molecular structure of the C4h isomer of YIII[Pc(?-OC5H11)4]2 Protonated (Phthalocyaninato)(porphyrinato) Rare Earth(III) Double-Decker Complexes J. Jiang* et al., Chem. Eur. J., 2006, 12, 1475. Molecular structure viewed along the C4 axis. [SmIII{Pc(?-OC5H11)4}(TClPP)] [SmIIIH{Pc(?-OC5H11)4}(TClPP)] [SmIII{Pc(?-OC5H11)4}(TClPP)] [SmIIIH{Pc(?-OC5H11)4}(TClPP)] J. Jiang* et al., Chem. Eur. J., In press.