continuous-flow processes in heterogeneously catalyzed transformations of biomass derivatives into fuels and chemicals在不同类地连续流动过程催化转换生物质衍生品为燃料和化学品.pdfVIP
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continuous-flow processes in heterogeneously catalyzed transformations of biomass derivatives into fuels and chemicals在不同类地连续流动过程催化转换生物质衍生品为燃料和化学品
Challenges 2012, 3, 114-132; doi:10.3390/challe3020114 OPEN ACCESS challenges ISSN 2078-1547 /journal/challenges Review Continuous-Flow Processes in Heterogeneously Catalyzed Transformations of Biomass Derivatives into Fuels and Chemicals Juan Carlos Serrano-Ruiz *, Rafael Luque, Juan Manual Campelo and Antonio A. Romero Departamento de Química Orgánica, Universidad de Córdoba, Campus de Excelencia Internacional Agroalimentario CeiA3, Edificio Marie Curie (C-3), Ctra Nnal IV-A, Km 396, Córdoba E-14014, Spain; E-Mails: q62alsor@uco.es (R.L.); qo1capej@uco.es (J.M.C.); qo1rorea@uco.es (A.A.R.) * Author to whom correspondence should be addressed; E-Mail: jcserrano@ua.es ; Tel.: +34-957-211-050; Fax: +34-957-212-066. Received: 11 May 2012; in revised form: 19 June 2012 / Accepted: 11 July 2012 / Published: 12 July 2012 Abstract: Continuous flow chemical processes offer several advantages as compared to batch chemistries. These are particularly relevant in the case of heterogeneously catalyzed transformations of biomass-derived platform molecules into valuable chemicals and fuels. This work is aimed to provide an overview of key continuous flow processes developed to date dealing with a series of transformations of platform chemicals including alcohols, furanics, organic acids and polyols using a wide range of heterogeneous catalysts based on supported metals, solid acids and bifunctional (metal + acidic) materials. Keywords: flow chemistry; biomass; platform molecules; biofuels; biochemicals; h
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