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13车辆-热工学-3-temperature
Problem
Deduce the crude oil price and compare it with the
price of domestic gasoline. Is it cheaper in domestic
market than international market or vice verse?
Crude oil price is 91.67
dollar per barrel by WTI.
1 barrel = 42 gallon
1 gallon = 3.7854 L
The product ratio of
gasoline to crude oil is
5:6.
( )
1
International price of gasoline: 91.67 6.145 / (42 3.7854)× × × 5/6 = 4.25
Example
h i ld d llT e pr ce of go was 1248.1 o ar per ounce.
How much is it in RMB per gram?
1 ounce = 28.3 g
1 lbm =16 ounce
1 dollar = 6.145 yuan
1248.1 6.145 / 28.3× = 270.5
270.5 yuan per gram
2
1.4 Properties of a System
7 important properties for thermodynamic purposes:
property symbol
Pressure P
temperature T (page12)
mass m
specific volume v
specific internal energy u
ifi th l hspec c en a py
specific entropy s
3
4
Intensive property
Extensive property
Intensive property
i d d t f th f th t— are n epen en o e mass o e sys em.
E.g. — temperature,pressure, density(ρ), etc
Extensive property
— depends on the size or extent of the system.
E.g. — mass, volume(V), etc
5
Intensive property Extensive property
Specific property– per unit mass extensive property.
Specific property is an intensive properties.
specific volume, ν=V/m
specific internal energy, u=U/m
Extensive property Intensive property
internal energy U specific internal energy u
volume V specific volume v
enthalpy H specific enthalpy h
entropy S specific entropy s
6
Basic test for ex- intensive
properties
Divide the system to two equal
parts with an imaginary
partition, the value of a
property remains the same,
it i i t i t s n ens ve proper y.
If the value changed to the
half of previous it is ,
extensive property.
7(page12)
Continuum– Matter is viewed as continuous and
homogenous with no holes.
The continuum idealization is valid as long as
h i f h i l l i ht e s ze o t e system s arge re at ve to t e
space between the molecules.
Note: In this text we will limit ou
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