附录Ⅵ-物质的标准摩尔生成焓、标准摩尔生成吉.docVIP

附录Ⅵ-物质的标准摩尔生成焓、标准摩尔生成吉 附录Ⅵ 物质的标准摩尔生成焓、标准摩尔生成吉 布斯函数、标准摩尔熵和摩尔热容(100kPa) (1)单质和无机物 　物质 　ΔfHmy(298.15K) 　ΔfGmy(298.15K) Smy(298.15K) Cp,my(298.15K) kJ·mol-1 kJ·mol-1 J·K-1mol-1 J·K-1·mol-1 Ag(s) 0 0 42.712 25.48 Ag2CO3(s) -506.14 -437.09 167.36 　 Ag2O(s) -30.56 -10.82 121.71 65.57 Al(s) 0 0 28.315 24.35 Al(g) 313.80 273.2 164.553 　 Al2O3-α -1669.8 -2213.16 0.986 79.0 Al2(SO4)3(s) -3434.98 -3728.53 239.3 259.4 Br2(g) 111.884 82.396 175.021 　 Br2(g) 30.71 3.109 245.455 35.99 Br2(l) 0 0 152.3 35.6 C(g) 718.384 672.942 158.101 　 C(金刚石) 1.896 2.866 2.439 6.07 C(石墨) 0 0 5.694 8.66 CO(g) -110.525 -137.285 198.016 29.142 CO2(g) -393.511 -394.38 213.76 37.120 Ca(s) 0 0 41.63 26.27 CaC2(s) -62.8 -67.8 70.2 62.34 CaCO3(方解石) -1206.87 -1128.70 92.8 81.83 CaCl2(s) -795.0 -750.2 113.8 72.63 CaO(s) -635.6 -604.2 39.7 48.53 Ca(OH)2(s) -986.5 -896.89 76.1 84.5 CaSO4(硬石膏) -1432.68 -1320.24 106.7 97.65 Cl-(aq) -167.456 -131.168 55.10 　 Cl2(g) 0 0 222.948 33.9 Cu(s) 0 0 33.32 24.47 CuO(s) -155.2 -127.1 43.51 44.4 Cu2O-α -166.69 -146.33 100.8 69.8 F2(g) 0 0 203.5 31.46 Fe-α 0 0 27.15 25.23 S(斜方) 0 0 31.9 22.60 (g) 124.94 76.08 227.76 32.55 S(g) 222.80 182.27 167.825 　 SO2(g) -296.90 -300.37 248.64 39.79 SO3(g) -395.18 -370.40 256.34 50.70 SO42- (aq) -907.51 -741.90 17.2 　 (2)有机化合物 　物质 　ΔfHmy(298.15K) 　ΔfGmy(298.15K) Smy(298.15K) Cp,my(298.15K) kJ·mol-1 kJ·mol-1 J·K-1mol-1 J·K-1·mol-1 　烃　　　类 CH4(g),　甲烷 -74.847 50.827 186.30 35.715 C2H2(g),　乙炔 226.748 209.200 200.928 43.928 C2H4(g),　乙烯 52.283 68.157 219.56 43.56 C2H6(g),　乙烷 -84.667 -32.821 229.60 52.650 C3H6(g),　丙烯 20.414 62.783 267.05 63.89 C3H6(g),　丙烷 -103.847 -23.391 270.02 73.51 C4H6(g),　1,3-丁二烯 110.16 150.74 278.85 79.54 C4H8(g),　1-丁烯 -0.13 71.60 305.71 85.65 C4H8(g),　顺-2-丁烯 -6.99 65.96 300.94 78.91 C4H8(g),　反-2-丁烯 -11.17 63.07 296.59 87.82 C4H8(g),　2-甲基两烯 -16.90 58.17 293.70 89.12 C4H10(g),　正丁烷 -126.15 -17.02 310.23 97.45 C4H10(g),　异丁烷 -134.52 -20.79 294.75 96.82 C6H6(g),　苯 82.927 129.723 269.31 81.67 C6H6(l),　苯 49.028 124.597 172.35