biomass steam gasification with in-situ co2 capture for enriched hydrogen gas production a reaction kinetics modelling approach生物质蒸汽气化与原位二氧化碳捕捉丰富的氢气生产反应动力学建模方法.pdfVIP
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biomass steam gasification with in-situ co2 capture for enriched hydrogen gas production a reaction kinetics modelling approach生物质蒸汽气化与原位二氧化碳捕捉丰富的氢气生产反应动力学建模方法
Energies 2010, 3, 1472-1484; doi:10.3390/en3081472 OPEN ACCESS energies ISSN 1996-1073 /journal/energies Article Biomass Steam Gasification with In-Situ CO Capture for 2 Enriched Hydrogen Gas Production: A Reaction Kinetics Modelling Approach Abrar Inayat, Murni M. Ahmad *, Suzana Yusup and Mohamed Ibrahim Abdul Mutalib Department of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Malaysia; E-Mails: abrar.inayat@ (A.I.); drsuzana_yusuf@.my (S.Y.); ibrahmat@.my (M.I.A.M.) * Author to whom correspondence should be addressed; E-Mail: murnim@.my; Tel.: +60-5-368 8208; Fax: +60-5-365 8204. Received: 9 July 2010; in revised form: 21 July 2010 / Accepted: 26 July 2010 / Published: 18 August 2010 Abstract: Due to energy and environmental issues, hydrogen has become a more attractive clean fuel. Furthermore, there is high interest in producing hydrogen from biomass with a view to sustainability. The thermochemical process for hydrogen production, i.e. gasification, is the focus of this work. This paper discusses the mathematical modeling of hydrogen production process via biomass steam gasification with calcium oxide as sorbent in a gasifier. A modelling framework consisting of kinetics models for char gasification, methanation, Boudouard, methane reforming, water gas shift and carbonation reactions to represent the gasification and CO2 adsorption in the gasifier, is developed and implemented in MATLAB
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