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Chapter
17
EffectoftheEnvironment
17.1Introduction
Foranadhesiveorsealantbondtobeuseful,itnotonlymustwith-
standthemechanicalforcesthatareactingonit,butitmustalsoresist
theelementstowhichitisexposedduringservice.Thus,oneofthe
mostimportantcharacteristicsofanadhesivejointorsealantisits
endurancetotheoperatingenvironment.Thisenduranceisalso
referredtoasthejoint’spermanenceordurability.Strengthandper-
manenceareinfluencedbymanycommonenvironmentalelements.
Theseincludehighandlowtemperatures,moistureorrelativehu-
midity,chemicalfluids,andoutdoorweathering.Table17.1summa-
rizestherelativeresistanceofvariousadhesivetypestocommonop-
eratingenvironments.
Theeffectofsimultaneousexposuretobothmechanicalstressanda
chemicalenvironmentisoftenmoreseverethanthesumofeachfactor
takenseparately.Mechanicalstress,elevatedtemperatures,andhigh
relativehumiditycanbeafatalcombinationforcertainadhesivesand
sealantsifalloccuratthesametime.Addtothisthepossiblecyclic
effectsofeachfactor,andonecaneasilyseewhyitisimportantto
understandtheeffectsofenvironmentonthejoint.
Environmentalconsequencesaresoseverethatitisusuallyneces-
sarytotestpreproductionjoints,bothinthelaboratoryandinthefield,
andundercondit
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