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COMMUNICATION
Sodium-IonBatterieswww.advmat.de
FormationofHierarchicalCu-DopedCoSeMicroboxesvia
2
SequentialIonExchangeforHigh-PerformanceSodium-Ion
Batteries
YongjinFang,Xin-YaoYu,*andXiongWen(David)Lou*
strategyistosynthesizemetalselenide
Electrodematerialsbasedonelectrochemicalconversionreactionshaveandcarbonnanocomposites.Forexample,
receivedconsiderableinterestforhighcapacityanodesofsodium-ionbat-Parketal.havesynthesizedCoSe2nano-
teries.However,theirpracticalapplicationisgreatlyhinderedbythepoorparticlesembeddedinN-dopedporous
ratecapabilityandrapidcapacityfading.Tuningthestructureatnanoscalecarbonmatrixwithenhancedcyclingsta-
bilityandhighratecapability.[14]
andincreasingtheconductivityoftheseanodematerialsaretwoeffectiveHierarchicalhollownanostructured
strategiestoaddresstheseissues.Herein,atwo-stepion-exchangemethodismaterialswithhighsurfaceareaand
developedtosynthesizehierarchicalCu-dopedCoSe2microboxesassembleduniquestructuresshowpromisingproper-
byultrathinnanosheetsusingCo–CoPrussianblueanaloguemicrocubestiesinhigh-performance
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