芘基联接的葡萄糖酸凝胶剂pyrenyl-linker-glucono gelators. correlations of gel-支持数据.pdfVIP

Supporting Information for PyrenylLinkerGlucono Gelators. Correlations of Gel Properties with Gelator Structures and Characterization of Solvent Effects †,‡ † § § *,† *,‡ Ni Yan, Zhiyan Xu, Kevin K. Diehn, Srinivasa R. Raghavan, Yu Fang, and Richard G. Weiss †Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education), School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an 710062, P. R. China ‡Department of Chemistry, Georgetown University, Washington, D.C. 200571227, United States §Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, MD 207422111, United States Table of Contents 1. Syntheses of gluconobased pyrenylcontaining compounds Error! Bookmark not defined. 2. Tgel values of 1decanol gels as a function of P7 concentration. 9 3. Table of Hansen solubility parameters of the liquids examined and the CGCs of P3 10 4. Hansen spaces of P2P8 in liquids 11 5. Plots of CGCs of Pn as a function of HSPs 14 6. TEM image prepared from a dried 0.02% P7 in acetonitrile sol. 16 7. Static contact angle (θ) measured on water for a xerogel film of P7 from acetonitrile 16 8. Xray diffraction patterns of neat Pn and calculated extended molecular lengths 17 9. Xray diffraction patterns of neat, xerogel and gel of P7 19 10. The evolution of molecular packing of P7 in acetonitrile leading to gels 19 11. Reversible variation of the CD intensity at 295 nm between the sol and gel phases 20 12. Fluorescence excitation spectra of 1.5% P7 in acetonitrile 20 13. Fluorescence emission spectra of 1.5% P7 in aceton