DEVELOPMENTOF HEALTHBASED ALTERNATIVE TO THE TOTAL PETROLEUM总的healthbased替代石油的发展.doc

INTERIM FINAL PETROLEUM REPORT: DEVELOPMENT OF HEALTH-BASED ALTERNATIVE TO THE TOTAL PETROLEUM HYDROCARBON (TPH) PARAMETER Prepared for: Bureau of Waste Site Cleanup Massachusetts Department of Environmental Protection Boston, MA Prepared by: Office of Research and Standards Massachusetts Department of Environmental Protection Boston, MA and ABB Environmental Services, Inc. Wakefield, MA AUGUST 1994 INTERIM FINAL PETROLEUM REPORT: DEVELOPMENT OF HEALTH-BASED ALTERNATIVE TO THE TOTAL PETROLEUM HYDROCARBON (TPH) PARAMETER TABLE OF CONTENTS Section Title Page No. EXECUTIVE SUMMARY v AUTHORS AND REVIEWERS ix 1.0 INTRODUCTION 11 1.1Background 11 1.2 Purpose 12 1.3 Approach 16 2.0 HAZARD IDENTIFICATION FOR PETROLEUM HYDROCARBONS 21 2.1 Composition of Petroleum Products 21 2.2 Toxic Effects of Whole Products 25 2.2.1Gasoline 25 2.2.1.1 Threshold Effects 27 2.2.1.2 Non-threshold Effects 27 2.2.2Diesel, Light Weight Fuel Oils and Jet Fuel 28 2.2.2.1 Threshold Effects 28 2.2.2.2 Non-threshold Effects 29 2.2.3No. 6 Fuel Oil 210 2.2.3.1 Threshold Effects 210 2.2.3.2 Non-threshold Effects 210 2.3 Toxic Effects of Selected Petroleum Component Compounds 211 2.3.1 Compounds with USEPA Approved DoseResponse Values 211 2.3.1.1 Threshold Effects 211 2.3.1.2 Non-threshold Effects 218 2.3.2 Other Petroleum Hydrocarbons 219 2.3.2.1 Availability of Chronic Toxicity Information 219 2.3.2.2 Availability of Acute Toxicity Information 225 2.3.3Summary of Available Toxicity Information 227 3.0 ASSIGNMENT OF TOXICITY INDICATOR VALUES FOR COMPONENTS OF PETROLEUM PRODUCTS 31 3.1Alkanes and Cycloalkanes 31 3.2Aromatics and Alkenes 36 3.2.1Threshold Effects 36 3.2.2Non-threshold Effects 37 4.0 DEVELOPMENT OF ALTERNATIVE ANALYTICAL TECHNIQUE 41 4.1Introduction 41 4.2Currently Available Methods 41 4.2.1Gravimetric Methods 41 4.2.2Infra-Red and Ultra-Violet Methods 43 4.2.3Gas Chromatography Methods 43 4.2.4Methods for Separating