studies of modified hydrogen storage intermetallic compounds used as fuel cell anodes改性的研究储氢金属间化合物化合物用作燃料电池阳极.pdfVIP
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studies of modified hydrogen storage intermetallic compounds used as fuel cell anodes改性的研究储氢金属间化合物化合物用作燃料电池阳极
Crystals 2012, 2, 22-33; doi:10.3390/cryst2010022 OPEN ACCESS crystals ISSN 2073-4352 /journal/crystals Article Studies of Modified Hydrogen Storage Intermetallic Compounds Used as Fuel Cell Anodes 1 1 1 2, Yun Chen , Diogo M. F. Santos , César A. C. Sequeira and Rui F. M. Lobo * 1 ICEMS, Instituto Superior Técnico, TULisbon, Av. Rovisco Pais, 1049–001 Lisboa, Portugal 2 ICEMS, Nanoscale Science Group, Physics Department FCT / UNL, 2829-516 Caparica, Portugal * Author to whom correspondence should be addressed; E-Mail: rfl@fct.unl.pt. Received: 6 September 2011; in revised form: 13 December 2011 / Accepted: 22 December 2011 / Published: 28 December 2011 Abstract: The possibility of substituting Pt/C with the hydrogen storage alloy MlNi3.6Co0.85Al0.3Mn0.3 as the anode active material of a proton exchange membrane fuel cell system has been analyzed. The electrochemical properties indicate that a much more electrochemically active anode is obtained by impregnating the active material loaded anode in a Nafion proton conducting polymer. Such performance improvement might result from the increase of three-phase boundary sites or length in the gas diffusion electrode where the electrochemical reaction occurs. The experimental data revealed that the membrane electrode assembly (MEA) shows better results when the anod
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