adsorption and quantum chemical studies on the inhibition potentials of some thiosemicarbazides for the corrosion of mild steel in acidic medium吸附和量子化学研究的一些氨基硫脲抑制势低碳钢在酸性介质的腐蚀.pdfVIP
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adsorption and quantum chemical studies on the inhibition potentials of some thiosemicarbazides for the corrosion of mild steel in acidic medium吸附和量子化学研究的一些氨基硫脲抑制势低碳钢在酸性介质的腐蚀
Int. J. Mol. Sci. 2010, 11, 2473-2498; doi:10.3390/ijm
OPEN ACCESS
International Journal of
Molecular Sciences
ISSN 1422-0067
/journal/ijms
Article
Adsorption and Quantum Chemical Studies on the Inhibition
Potentials of Some Thiosemicarbazides for the Corrosion of
Mild Steel in Acidic Medium
Eno E. Ebenso 1,*, David A. Isabirye 1 and Nnabuk O. Eddy 2
1 Department of Chemistry, North West University (Mafikeng Campus), Private Bag X2046,
Mmabatho 2735, South Africa
2 Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria
* Author to whom correspondence should be addressed; E-Mail: Eno.Ebenso@nwu.ac.za;
Tel.: (+27)-18-389-2113; Fax: (+27)-18-389-2052.
Received: 8 May 2010; in revised form: 22 May 2010 / Accepted: 23 May 2010 /
Published: 15 June 2010
Abstract: Three thiosemicarbazides, namely 2-(2-aminophenyl)-N
phenylhydrazinecarbothioamide (AP4PT), N,2-diphenylhydrazinecarbothioamide (D4PT)
and 2-(2-hydroxyphenyl)-N-phenyl hydrazinecarbothioamide (HP4PT), were investigated
as corrosion inhibitors for mild steel in H SO solution using gravimetric and gasometric
2 4
methods. The results revealed that they all inhibit corrosion and their % inhibition
efficiencies (%IE) follow the order: AP4PT HP4PT D4PT. The %IE obtained from the
gravimetric and gasometric experiments were in good
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