桦甸页岩油柴油馏分加氢精制生产清洁燃料油的研究_于航.pdfVIP

38 3 V .l 38 N . 3 2010 6 J urnal f Fuel Chem istry and T echn l gy Jun. 2010 : 0253-2409( 20 10) 03-05-297 1 1 2 1 于 航 , 李术元, 靳广洲 , 唐 勋 ( 1. () , 102249; 2. , 102617) : ( 200 e ~ 360 e ) 4 1% , , , C M /A l O 2 3 N Wi /A l O , , 2 3 , , , , , , , , , N Wi /A l O C M /A l O , 2 3 2 3 , , , : ; ; ; : TE662. 8 : A H ydrotreating of the d iesel d istillate from H uad ian shale oil for production of clean fuel 1 1 2 1 YU Hang , L I Shu-yuan , JIN Guang-zh u , TANG Xun ( 1. S tate K ey Laboratory of H eavy O il P rocessing, China University of Petroleum (Beij ing , B eij ing 102249, China; 2. D ep artm ent of Chem ical Eng ineer ing, B eij ing Institute of Petrochem ical Techno logy, B eij ing 1026 17, China Abs tract: The d iesel d istillate ( 200 e ~ 360 e ) acc unting f r ab ut 41% in Huad ian shale il has higher su lphur, nitr gen and alkene c nten ts. The main su lphur-c ntain ing c mp unds in the diesel distillate are BTs ( benzylthi phene) and DBTs ( di benzylthi phene), and the c n tent f basic n itr gen c mp und in the d istillate appr aches t that f n nbasic nitr gen c mp und. In rder t pr duce a clean fue,l the catalytic hydr treating f diesel fracti n fr m Huad ian shale il w as investigated prelmi inarily in a fixed bed react r using tw k ind f c mmercial catalysts including C M /A l O and N Wi /A l O at different temperatures, hydr gen pressures, L