氧化石墨烯在各种有机溶剂中的溶解性.pdfVIP

氧化石墨烯在各种有机溶剂中的溶解性.pdf

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氧化石墨烯在各种有机溶剂中的溶解性

10560 Langmuir 2008, 24, 10560-10564 Graphene Oxide Dispersions in Organic Solvents J. I. Paredes,* S. Villar-Rodil, A. Martı´nez-Alonso, and J. M. D. Tasco´n Instituto Nacional del Carbo´n, CSIC, Apartado 73, 33080 OViedo, Spain Recei Ved June 5, 2008. ReVised Manuscript ReceiVed August 5, 2008 The dispersion behavior of graphene oxide in different organic solvents has been investigated. As-prepared graphite oxide could be dispersed in N,N-dimethylformamide, N-methyl-2-pyrrolidone, tetrahydrofuran, and ethylene glycol. In all of these solvents, full exfoliation of the graphite oxide material into individual, single-layer graphene oxide sheets was achieved by sonication. The graphene oxide dispersions exhibited long-term stability and were made of sheets between a few hundred nanometers and a few micrometers large, similar to the case of graphene oxide dispersions in water. These results should facilitate the manipulation and processing of graphene-based materials for different applications. 1. Introduction implementation of solution-phase techniques toward the conver- 2 sion of graphene oxide back to graphene by way of chemical Graphene, the 2D lattice of sp -bonded carbon atoms from 10,11 reduction or the processing of the graphene oxide sheets into which graphite, carbon nanotubes, and fullerenes are derived,

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