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Microwave assisted exfoliation and reduction of graphite oxide for ultracapacitors
(HK) methods. Further studies are needed to control the pore size distributions for specific applications, for example, increasing micropore volume for hydrogen storage. In summary, using SiCx fibres derived from the pyrolysis of the hybrid precursor fibres of PCS and pitch, a proper control of the activation conditions can yield the co-axial porous composite fibres with high SSA. The porosity and component of the activated fibres may be adjusted by facile control the activation conditions. This kind of core–shell structured fibres can be regarded as Si-substituted activated carbon fibres, which may be promising functional materials, for example, as potential hydrogen storage materials and catalyst sup- ports. This approach can also be adopted for the preparation of M-substituted activated carbon fibres if M-containing poly- mers (or blends) are used as the starting material. Acknowledgement The authors gratefully acknowledge financial support of Na- tional Natural Science Foundation of China (No.. Appendix A. Supplementary data Supplementary data associated with this article can be found, in the online version, at doi:10.1016/j.carbon.2010.01.064. R E F E R E N C E S [1] Mandal TK, Gregory DH. Hydrogen storage materials: present scenarios and future directions. Annu Rep Prog Chem Sect A 2009;105:21–54. [2] Lee J, Kim J, Hyeon T. Recent progress in the synthesis of porous carbon materials. Adv Mater 2006;18(16):2073–9. [3] Wang HL, Gao QM, Hu J. High hydrogen storage capacity of porous carbons prepared by using activated carbon. J Am Chem Soc 2009;131(20):7016–22. [4] Gogotsi Y, Welz S, Ersoy DA, McNallan MJ. Conversion of silicon carbide to crystalline diamond-structured carbon at ambient pressure. Nature (London) 2001;411(6835):283–7. [5] Thomas KM. Adsorption and desorption of hydrogen on metal – organic framework materials for storage applications: comparison with other nanoporous materials. Dalton Trans 2009;9:1487–505. [6] Chung TCM, Jeong Y, Chen Q,
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