Fabrication and performance of anode-supported solid oxide fuel cells via slurry spin coating.pdfVIP
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Fabrication and performance of anode-supported solid oxide fuel cells via slurry spin coating
F s M a b a A R R A A K S P A C P 1 h t a m w m i p e t m e t t t s t S 0 dJournal of Membrane Science 360 (2010) 461–468 Contents lists available at ScienceDirect Journal of Membrane Science journa l homepage: www.e lsev ier .com/ locate /memsci abrication and performance of anode-supported solid oxide fuel cells via lurry spin coating in Chena, Bok Hee Kima,?, Qing Xub,??, Byung Guk Ahna, Duan Ping Huangb Department of Hydrogen and Fuel Cells Engineering, Hydrogen Fuel Cell Research Center, Chonbuk National University, Jeonju, Jeonbuk 561-756, South Korea School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, PR China r t i c l e i n f o rticle history: eceived 2 April 2010 eceived in revised form 12 May 2010 ccepted 20 May 2010 vailable online 27 May 2010 eywords: a b s t r a c t Ce0.8Sm0.2O1.9 (SDC) dense electrolyte thin film, La0.6Sr0.4Co0.2Fe0.8O3?? (LSCF) porous cathode layer and Ni–SDC anode functional layer for anode-supported SOFCs are fabricated by a slurry spin coating tech- nique. The optimum conditions for preparing the single cell with a uniform microstructure as well as excellent performance have been investigated. A dense electrolyte thin filmwith a crack-freemicrostruc- ture can be obtained by using the SDC powders pre-calcined at 900 ?C. The power density of the cells increases with the increasing weight content of corn starch (corn starch wt.%), which is mainly ascribedlurry spin coating ore former node functional layer oncentration loss olarization resistance to the decrease of the concentration loss in the anode. However, the trade-off between the single cell performance andmechanical strength results in the optimumcomposition being obtained for theNi–SDC anode containing 15wt.% corn starch (15-Ni–SDC). In contrast to the data in the literatures, the relatively large ohmic resistance (Rohm) values in the present study are obtained for the 15-Ni–SDC cell. In order to further improve the cell performance, an
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