2015年荐737~744.docVIP

737～744 *通讯联系人: 曾昭睿, 教授, 博士生导师, 研究方向为毛细管电色谱、固相微萃取. Tel: (027 E-mail: zrzeng@. 基金项目: 国家自然科学基金项目(No.. 收稿日期: 2009-06-25 超分子化合物毛细管电色谱固定相的研究进展 田耘1, 曹小敏3, 张琪1, 曾昭睿2* (1.湖南省环境监测中心站, 湖南 长沙 410014; 2.武汉大学化学与分子科学学院, 湖北 武汉 430072; 3.长沙环境保护职业技术学院, 湖南 长沙 410004) 摘要: 超分子化学是一门研究分子间特定识别能力的新兴学科,超分子化合物所具有的主-客体识别能力为高选择性的色谱分离提供了广阔的发展前景。毛细管电色谱是近年来发展起来的一种高效、高选择性的微分离技术,电色谱固定相是该技术的核心部分,一直是研究的热点。本文综述了1998年以来环糊精、杯芳烃、冠醚以及大环多胺等4种超分子化合物用作毛细管电色谱固定相的研究进展情况。 关键词: 超分子化合物;毛细管电色谱;固定相 文章编号: 1000-8713(2009)06-0737-08栏目类别: 专论与综述 Research progress in supramolecular compounds-based stationary phases for capillary electrochromatography TIAN Yun1, CAO Xiaomin3, ZHANG Qi1, ZENG Zhaorui2* (1.Hunan Environmental Monitoring Center, Changsha 410004, China; 2.College of Chemistry and Molecule Science, Wuhan University, Wuhan 430072, China; 3.Changsha Environmental Protection Vocational College, Changsha 410004, China) Abstract: Supramolecular chemistry is a new branch of sciences, which deals with the specific recognitions between molecules. The host-guest interactions, which exert by supramolecular compounds, can provide a promising prospect for chromatographic separations with high selectivities. Capillary electrochromatography (CEC) is defined as a very promising micro-separation technique with high efficiency and high selectivity in recent years. As the key component of CEC, the stationary phases have been the research focus of CEC development. This paper reviews the recent progress in supramolecular compounds-based stationary phases (cyclodextrin, calixarene, crown ether and macrocyclic polyamine) for CEC since 1998. Key words: supramolecular compounds; capillary electrochromatography (CEC); stationary phases 745～749 *Corresponding author: XU Zhenghong, professor. Research area: biopharmaceutics. Tel: (0510 E-mail: zhenghxu@.Foundation item: This work was supported by National High-Tech Program of China (No. 2007AA021506), National Basic Research Program of China (No. 2007CB707