生物酶催化聚合的研究进展-生物技术通报.PDFVIP

生物技术通报 BIO TE CHN OLOG Y B ULLETIN 2010 4 1 1 1 1 1 2 1 马艳芬 吕生华 刘岗 董凌霄 李芳 王飞 郑新建 1 2 ( , 710021; , 710021) : 酶催化聚合反应是近年来的研 热点之一, 氧化还原酶是应用广泛的一类催化聚合酶概括总结了近年来酶 促聚合反应的研 进展, 重点叙述了辣根过氧化物酶(HRP)大豆过氧化物酶( SBP)和漆酶( laccase)的结构催化机理以及它 们在酶催化聚合中的应用概况 : 酶催化 辣根过氧化物酶 大豆过氧化物酶 漆酶 R esearch P rogress of the Enzym atic P olym erization 1 1 1 1 1 2 1 MaYanfen Lv Shenghua L iu Gang ong Lingxiao LiFang W ang Fei Zheng Xinjian 1 2 ( Colleg e of R esource and E nv ironm en,t Shaanx i University of Science Technology, X i an 710021; Colleg e of M aterials Science and E ng ineering, Shaanx i University of Science Technology, X i an 710021 Abstrac:t Enzymecatalyzed polymerization is one of the research focus in recent years, and oxidoreductases have showed that w ide applications in catalytic synthesisofpolymer. This paper described the research progress of enzymecatalyzed polymerization in re cent years, andmainly discussed that the structure, catalyticmechanism ofhorseradish peroxidase, soybean perox idase and laccase, as well as their application situation in enzymecatalyzed polymerization. K ey w ords: Enzyme catalysis Horseradish peroxidase Soybean peroxidase Laccase , 1 [ 1] ( horseradish peroxidase, HRP) , , [ 2] 1985, Klibanov