富勒烯材料的催化作用研究进展3.PDF

第 18 卷 第 6 期 化　学　进　展 Vol. 18 No. 6 2006 年 6 月 PROGRESS IN CHEMISTRY 　June , 2006 富勒烯材料的催化作用研究进展 韩　旭　李疏芬 ( 中国科学技术大学化学物理系 　合肥 230026) ( ) 摘 　要 　介绍了富勒烯材料 富勒烯和富勒烯衍生物 的催化作用研究进展 ,特别是催化有机反应方面 , 包括催化氢转移和硅氢化反应、烷烃裂解反应、氢氘互换反应、耦合和烷基转移反应等。这种新材料还可以 (1 ) 催化产生单线态氧 O2 的化学反应、催化非金属固氮反应、催化石墨合成金刚石的反应 , 同时还可催化高能 燃料的燃烧过程 ,具有广泛的应用前景。 关键词 　富勒烯 　催化剂 　催化作用 ( ) 中图分类号: O64332 　文献标识码 : A 　文章编号 : 1005281X 2006 Advances in Catalytic Function of Fullerene Materials Han Xu 　Li Shufen (Department of Chemiscal Physics , Science and Technology University of China , Hefei 230026 , China) Abstract 　The applications of fullerene materials (including fullerenes and fullerenebased materials) in catalytic reactions , especially in organic reactions , including application in hydrogen transfer and hydrosilylation , pyrolysis of alkanes , H D exchange , coupling and alkyl transfer reaction are reviewed in this paper. Singlet oxygen reaction , non 2 2 metal nitrogenfixation reaction , graphitediamond phase transition process and highenergy materials combustion processes could be also catalyzed by these new materials. All reactions showed very good catalytic functionality. Key words 　fullerenes ; catalysts ; catalytic functionality