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demospongic acids revisiteddemospongic酸重新审视
Mar. Drugs 2010, 8, 2569-2577; doi:10.3390/md8102569 OPEN ACCESS Marine Drugs ISSN 1660-3397 /journal/marinedrugs Review Demospongic Acids Revisited Jean-Michel Kornprobst * and Gilles Barnathan Groupe Mer, Molécules, Santé MMS/EA 2160, Equipe 7: Lipides marins à activité biologique, Pôle Mer et Littoral, Faculté de Pharmacie, Université de Nantes, France; E-Mail: gilles.barnathan@univ-nantes.fr * Author to whom correspondence should be addressed; E-Mail: jean-michel.kornprobst@univ- nantes.fr; Tel.: +33 2 51 12 56 89; Fax: +33 2 51 12 56 79. Received: 7 September 2010; in revised form: 27 September 2010 / Accepted: 30 September 2010 / Published: 8 October 2010 Abstract: The well-known fatty acids with a 5,9 unsaturation system were designated for a long period as demospongic acids, taking into account that they originally occurred in marine Demospongia sponges. However, such acids have also been observed in various marine sources with a large range of chain-lengths (C –C ) and from some terrestrial 16 32 plants with short acyl chains (C –C ). Finally, the 5,9 fatty acids appear to be a 18 19 particular type of non-methylene-interrupted fatty acids (NMA FAs). This article reviews the occurrence of these particular fatty acids in marine and terrestrial organisms and shows the biosynthetic connections between 5,9 fatty acids and other NM
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