coordination of {mo142} ring to la3+ provides elliptical {mo134la10} ring with a variety of coordination modes协调{ mo142 }环la3 +为椭圆{ mo134la10 }环提供了各种各样的协调模式.pdfVIP
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coordinationof{mo142}ringtola3provideselliptical{mo134la10}ringwithavarietyofcoordinationmodes协调{mo142}环la3为椭圆{mo134la10}环提供了各种各样的协调模式
Materials 2010, 3, 64-75; doi:10.3390/ma3010064 OPEN ACCESS materials ISSN 1996-1944 /journal/materials Article Coordination of {Mo142} Ring to La3+ Provides Elliptical {Mo134La10} Ring with a Variety of Coordination Modes Eri Ishikawa 1,2, Yutaka Yano 1,3 and Toshihiro Yamase 1,4,* 1 Chemical Resources Laboratory, Tokyo Institute of Technology, R1-21, 4259 Nagatsuta, Midori- ku, Yokohama 226–850, Japan 2 Department of Applied Chemistry, College of Engineering, Chubu University, 1200 Matsumoto, Kasugai, Aichi 487–8501, Japan; E-Mail: eishikawa@isc.chubu.ac.jp (E.I.) 3 Matsuda Sangyo Co., Ltd., Shinjuku Nomura Building 6th Fl., 1-26-2 Nishishinjuku, Shinjuku-ku, Tokyo 163–0558, Japan; E-Mail: yano-y@matsuda-sangyo.co.jp (Y.Y.) 4 (Inc.) MO Device, 2-14-10 Kanaiwa-higashi, Kanazawa 920–0335, Japan * Author to whom correspondence should be addressed; E-Mail: yamase.modevice@; Fax: +81-76-267-0468. Received: 29 November 2009; in revised form: 23 December 2009 / Accepted: 25 December 2009 / Published: 28 December 2009 Abstract: A 28-electron reduced C2h-Mo-blue 34Ǻ outer ring diameter circular ring, [Mo O H (H O) (CH CO ) (C H CO )]30- (≡{Mo (CH CO ) (C H CO )}) 142 429 10 2 49 3 2 5 2 5 2 142 3 2 5 2 5 2 comprising eight carboxylate-coordinated (with disorder) {Mo2 } linkers and six defect pockets in two inner rings (four and three for each, respecti
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