spontaneous deposition of prussian blue on multi-walled carbon nanotubes and the application in an amperometric biosensor普鲁士蓝的自发沉积多壁碳纳米管和应用程序在一个安培计的生物传感器.pdfVIP
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spontaneous deposition of prussian blue on multi-walled carbon nanotubes and the application in an amperometric biosensor普鲁士蓝的自发沉积多壁碳纳米管和应用程序在一个安培计的生物传感器
Nanomaterials 2012, 2, 428-444; doi:10.3390/nano2040428 OPEN ACCESS nanomaterials ISSN 2079-4991 /journal/nanomaterials Article Spontaneous Deposition of Prussian Blue on Multi-Walled Carbon Nanotubes and the Application in an Amperometric Biosensor Yanli Yao, Xiaoyun Bai and Kwok-Keung Shiu * Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong; E-Mails: xli0207@ (Y.Y.);.hk (X.B.) * Author to whom correspondence should be addressed; E-Mail: kkshiu@.hk; Tel.: +852-3411-7346; Fax: +852-3411-7348. Received: 16 October 2012; in revised form: 16 November 2012 / Accepted: 16 November 2012 / Published: 27 November 2012 Abstract: A simple method has been developed for the spontaneous deposition of Prussian blue (PB) particles from a solution containing only ferricyanide ions onto conducting substrates such as indium tin oxide glass, glassy carbon disk and carbon nanotube (CNT) materials. Formation of PB deposits was confirmed by ultraviolet-visible absorption spectrometry and electrochemical techniques. The surface morphology of the PB particles deposited on the substrates was examined by atomic force microscopy and scanning electron microscopy. CNT/PB composite modified glassy carbon electrodes exhibited an electrocatalytic property for hydrogen peroxide reduction. These modified electrodes exhibited a high sensitivity for electrocatalytic reduction of hydrogen peroxide at −0.05 V (vs. Ag|AgCl), probably due to the
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