solvent vapor treatment effects on poly(3-hexylthiophene) thin films and its application for interpenetrating heterojunction organic solar cells溶剂蒸汽处理对聚(3-hexylthiophene)薄膜及其应用贯穿异质结有机太阳能电池.pdfVIP

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solvent vapor treatment effects on poly(3-hexylthiophene) thin films and its application for interpenetrating heterojunction organic solar cells溶剂蒸汽处理对聚(3-hexylthiophene)薄膜及其应用贯穿异质结有机太阳能电池.pdf

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solvent vapor treatment effects on poly(3-hexylthiophene) thin films and its application for interpenetrating heterojunction organic solar cells溶剂蒸汽处理对聚(3-hexylthiophene)薄膜及其应用贯穿异质结有机太阳能电池

Materials 2010, 3, 4939-4949; doi:10.3390/ma3114939 OPEN ACCESS materials ISSN 1996-1944 /journal/materials Article Solvent Vapor Treatment Effects on Poly(3-hexylthiophene) Thin Films and its Application for Interpenetrating Heterojunction Organic Solar Cells Tetsuro Hori, Varutt Kittichungchit, Hiroki Moritou, Hitoshi Kubo, Akihiko Fujii * and Masanori Ozaki Division of Electrical, Electronic and Information Engineering, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan * Author to whom correspondence should be addressed; E-Mail: afujii@opal.eei.eng.osaka-u.ac.jp; Tel.: +81-6-6879-7758; Fax: +81-6-6879-7774. Received: 22 October 2010; in revised form: 8 November 2010 / Accepted: 12 November 2010 / Published: 15 November 2010 Abstract: The solvent vapor treatment (SVT) for poly(3-hexylthiophene) (PAT6) films and its application to interpenetrating heterojunction organic solar cells have been studied. It was found that SVT could improve the crystallinity and electrical characteristics of the PAT6 films. We fabricated organic solar cells with an interpenetrating structure of PAT6 and fullerenes utilizing the SVT process, and discuss the improved performance of the solar cells by taking the film crystallinity, optical properties, and morphology into consideration. Keywords: solvent vapor treatment; interpenetrating heterojunction; organic solar cells; poly(3-hexylthiophene); fullerene 1. Introduction