低黄变亲水性硅油的制备.pdfVIP

第28 卷第4 期 印染助剂 Vol．28 No．4 2011 年4 月 TEXTILE AUXILIARIES Apr．2011 低黄变亲水性硅油的制备 章 莹，刘维锦 （华南理工大学，广东广州 510640） 摘 要：以α,ω-二羟基聚二甲基硅氧烷(WS-62M)、环己基氨基硅烷和活性聚醚为原料,制备用于织物后整理的环氧聚醚改 性氨基硅油柔软剂.用红外光谱对其进行结构表征, 同时确定了优化的合成氨基聚醚共改性硅油工艺条件:仲氨型氨基硅油的合成温 度为85 ℃,n(环氧基聚醚)∶n(仲氨型氨基硅油)=0.7∶1.经其整理的白棉布手感、白度、亲水性均较好,且具有比传统改性硅油优越的吸水 性和抗黄变性. 关键词：α,ω-二羟基聚二甲基硅氧烷; 环己基氨基硅烷; 聚醚; 改性硅油 + 中图分类号: TQ264.1 7 文献标识码: A 文章编号: 1004－0439(2011)04－0022－03 Synthesis of low-yellowing hydrophilic silicone oil ZHANG Ying, LIU Wei-jin (South China University of Technology, Guangzhou 510640, China) Abstract ： Using α,ω -dihydroxydimethylpolysiloxane (WS-62M), cyclohexylaminosilane coupling agent and epoxy group polyether as raw materials, polyether modified aminopolysiloxane was synthesized, which was ap－ plied to fabric softening finish. The structure was characterized with IR spectrum. The optimum synthetic the e－ poxy polyether modified aminopolysilxane conditions were determined: the reaction temperature of secondary amino silicone oil synthesis was 85 ℃, and the molar ratio of epoxy polyether and amino silicone oil was 0.7 ∶1. The finished white cotton fabric had good handle, whiteness and hydrophility, and had better absorbency and an － ti-yellowing property than the traditional modified silicone oil. Key words ： α,ω-dihydroxydimethylpolysiloxane; cyclohexylaminosilane; polyether; modified silicone oil 氨基硅油能与织物纤维表面的羟基、羧基等相互 基氨基硅烷为偶联