新型三维微孔砷酸铟InAsO4(H2O)2的合成及结构-上海有机化学.PDF

2002 60 Vol .60, 2002 2 , 305 ～ 309 ACTA CHIM ICA SINICA No .2, 305～ 309 InAsO (H O) 4 2 2 陈珍霞　　翁林红　　周亚明　　张浩宇　　赵东元 (　 200433) 　, InAsO -1, 4 .X InAsO -1 InAsO (H O ).:Pbca, a=0.9090 (4 )nm, b= 4 4 2 2 3 1.0344(4 )nm, c=1.0468(4)nm, α=β=γ=90°, V=0.9843(7 )nm , Z=8, R=0.04 80, R =0.1045.InAsO -1 w 4 1 4 2 , a, b 4 6 , 8 6 4 . . 　, , , , Synthesis and Structure of A New Three-Dimensional Microporous Indium Arsenate CHEN, Zhen-X a 　　WENG, L n-Hong 　　ZHOU, Ya-M ng 　　ZHANG, Hao-Yu ZHAO, Dong-Yuan (Department of Chemistry, Fudan University, Shanghai 2004 ) Abstract　A new three-d mens onal m croporous nd um arsenate has been synthes zed for the f rst t me from the hydrothermal react on of H O, InCl ·4H O, H AsO and C H N ·6H O.S ngle crystal X-ray d ffract on 2 3 2 3 4 6 12 2 2 stud es show that t has an orthorhomb c (symmetry space group Pbca ), w th a=0.9090 (4 )nm, b=1.0344 (4 )nm, c=1.0468(4)nm .Its asymmetry un t s InAsO4 (H2O )2, wh ch produces a 4-r ng and 6-r ng 1D channel alo