金属有机骨架材料的合成及应用.pdf

17 化 学 进 展 Vol. 17 No. 2005 11 PROGRESS IN CHEMISTRY Nov. , 2005 金属有机骨架材料的合成及应用 * 魏文英 方 键 孔海宁 韩金玉 常贺英 ( 天津大学化工学院绿色合成与转化教育部重点 验室 天津300072) 金属有机骨架( MOFs) 材料是目前研究很热的一种新功能材料本文讨论了金属有机骨架材 料的设计原理制备过程骨架结构的影响因素以及骨架合成的发展状况, 总结了金属有机骨架材料在催化 剂气体的储存和分离方面的应用, 并对这种新型多功能材料在设计合成与应用中的广阔前景做了展望 金属有机骨架 配位聚合物 多孔材料 催化剂 气体储存 分离 : O 3; TB383 : A : 1005-281X( 2005) 0 -1110-0 Synthesis and Applications for Materials of Metallorganic Frameworks * Wei Weny ing Fang Jian Kong H aining H an Jiny u Chang Heying ( Key Laboratory for Green Chemical Technology of the Ministry of Education, School of Chemical Engineering Technology, Tianjin University, Tianjin 300072, China) Abstract Materials of metallorganic frameworks is a new kind of functional materials being largely researched now. The principles of design, preparation process, the factors effecting on the structure and the development status of synthesis for metallorganic frameworks(MOFs) are discussed. The applications of the new kind of poly-function materials in the aspect of catalyst, gas storage and separation are summarized. In addition, suggestions of the prospective design, synthesis and applications are presented. Key words metallorganic framework; coordination polymers; porous materials; catalysts; gas storage; separation , (MOFs) , , ( ) , 20 90 2 - 1[ 1] [ 2] , MOFs , 2 030m #g ,