全氟烷基磺酰亚胺配合物在均相与非均相催化反应中的应用.pdfVIP

第30 卷第2 期 高 校 化 学 工 程 学 报 No.2 Vol.30 2016 年 4 月 Journal of Chemical Engineering of Chinese Universities Apr. 2016 文章编号：1003-9015(2016)02-0253-08 全氟烷基磺酰亚胺配合物在均相与非均相催化反应中的应用 詹晓力, 唐永强, 何逸波, 张庆华, 陈丰秋 (浙江大学 化学工程与生物工程学院, 浙江 杭州 310027) 摘 要：普通的液体酸催化剂在应用过程中难免产生环境问题，而固体酸催化剂使用寿命短、活性低，全氟烷基磺酰 亚胺配合物因其特殊的阴离子结构以及所具有的超酸性质而在新型催化领域表现出广泛的应用前景。文章介绍了全氟 烷基磺酰亚胺配合物的结构与性能特点，综述了近年来全氟烷基磺酰亚胺配合物在催化领域的应用，重点阐述了在均 相催化与多相催化反应中的必威体育精装版进展，以期对其催化性能和应用前景有比较全面的认识。 关键词：全氟烷基磺酰亚胺；均相；非均相；催化 中图分类号：TQ032.4 文献标识码：A DOI ：10.3969/j.issn.1003-9015.2016.02.001 Review on the Application of Perfluoroalkylsulfonylimides Complexes in Homogeneous and Heterogeneous Catalysis ZHAN Xiao-li, TANG Yong-qiang, HE Yi-bo, ZHANG Qing-hua, CHEN Feng-qiu (College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China) Abstract: Traditional liquid acid catalysts have environmental problems during their application, while solid acid catalysts have drawbacks for their low activity and short service life. Perfluoroalkylsulfonylimides complexes show a wide application in catalysis due to their special anionic structures and super acid properties. The structure and properties of perfluoroalkylsulfonylimides complexes are introduced in this review and their application as catalysts in homogeneous and heterogeneous catalysts are summarized. The development trends of perfluoroalkylsulfonylimides complexes are also discussed. Key words: perfluoroalkylsulfonylimide; homogeneous; heterogeneous; catalysis O O 1 引 言 O