王积涛著《有机化学+》完整第二版课后习题答案.pdfVIP

???ZZZHNDRNDRFRP????_?????????? ????? 2011-7-24 ?????????? 1 ???ZZZHNDRNDRFRP????_?????????? ń ???BH3 HB H H ?????(BH3)???????????????????. BH3ЁB?sp2?? ????. ? ????CH2Cl2 HH ? Э?C2H6 HH H C Cl Cl H H H ????????: ????Ё?C – C? C – H????????. 2011-7-24 ?????????? 3 ???ZZZHNDRNDRFRP????_?????????? 4??????????2???1???1?? ?H2CO? ????????????? H HC O 5???CH3CH = CH2Ё??????sp3???? ??sp2??? CH3 - CH = CH2 sp3 sp2 sp2 2011-7-24 ?????????? 5 ???ZZZHNDRNDRFRP????_?????????? 8??????????????????咑???CO2?∈ ???HCO3-?H2CO3,??????????????? ?????????咑????? O=C=O ??????????????Ё??????????? ????????Ё??????????????ㄝ?? ???????????????????? OO HO 2011-7-24 C O- HO ?????????? C OH 7 ???ZZZHNDRNDRFRP????_?????????? 1?????????????????????? ???????? ? ??CHCl3 ? ???H2S H S C Cl Cl Cl H ? ??CH3NH2 H H 2011-7-24 ?????????? N H CH3 2 ???ZZZHNDRNDRFRP????_?????????? 2. ??3????П????????,???????? ?,±??p???????. ±??3??????? ??? HH HH 3????????,±???????3??????, ±????????,??3???. 3. ??CH3CH2CH3???????????,????? ??????. HH H H 2011-7-24 H HH ?????????? H 4 ???ZZZHNDRNDRFRP????_?????????? 6???????????Ё???? 3-? 3-? 3-? CH2 = CH - CH = CH2 ±-? ±-? 7????????CH3C CH Ё???????? ????sp??????? CH3C CH sp3 sp sp ?????????????????ぎ??????????? ?????????????2?sp????П???????1800?sp ?????????????? 2011-7-24 ?????????? 6 ???ZZZHNDRNDRFRP????_?????????? ????????????????? OO HO C -2H+ -O C OH O- ???Ё????????????????? ???????П?????H+??????? ????????〇??????????? ?? 2011-7-24 ?????????? 8 ???ZZZHNDRNDRFRP????_?????????? 9??￥+/￥-???????????????: ￥+ ￥- ￥+ ￥- ? H3C __ Br ? H3C __ NH2 ? ￥- H3C __ ￥+ Li ￥- ￥+ ń NH2 __ H ? ￥+ H3C __ ￥- OH ￥- ￥+ (6) H3C __ MgBr 10?H2N-????HO-????????????NH3 ?H2O?????????咑? ㄨ?H2O?????????????????? ???????????????????? ??H+?????? 2011-7-24 ?????????? 9 ???ZZZHNDRNDRFRP????_?????????? 12??NH3?pKa˙36???CH3COCH3?pKa˙20?????? = = ??????????? O CH3 _ C _ CH3 + Na+ ? - NH2 O CH3 _ C _ CH2- Na+ + NH3 ?? ?? ?? ?? ????????????????????? 13???